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| LETTER | Synlett 2006: 3343-3345
DOI: 10.1055/s-2006-951551 |
© Georg Thieme Verlag Stuttgart · New York
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Conjugate Reduction of α,β-Unsaturated Aldehydes with Rhodium(bisoxazolinylphenyl) Catalysts
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| Yoshinori Kanazawa, Hisao Nishiyama* |
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan
Fax: +81(52)7893209; e-Mail: hnishi@apchem.nagoya-u.ac.jp;
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Received
31 August 2006 |
Abstract
α,β-Unsaturated aldehydes were selectively reduced using rhodium(bisoxazolinylphenyl) complexes to give exclusive 1,4-selectivity in the combination of alkoxyhydrosilanes. Key words
rhodium - conjugate reduction - unsaturated aldehyde - hydrosilylation - asymmetric catalysis
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