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Fensterbank, L. et al.: 2021 Science of Synthesis, 2020/5: Free Radicals: Fundamentals and Applications in Organic Synthesis 2 DOI: 10.1055/sos-SD-233-00133
Free Radicals: Fundamentals and Applications in Organic Synthesis 2

2.7 Radical Cascade Reactions

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Book

Editors: Fensterbank, L.; Ollivier, C.

Authors: Bartulovich, C. O.; Bolduc, T. G.; Chciuk, T. V.; Chemla, F.; Clark, K. F.; Cormier, M.; Das, A. ; Desage-El Murr, M. ; Dimitrova, D.; Fagnoni, M. ; Flowers, R. A. II; Fukuyama, T. ; Goddard, J.-P. ; Hessin, C.; Liu, Z.-Q. ; Lu, Y.; Mitsudo, K.; Murphy, J. A.; Pérez-Luna, A. ; Protti, S. ; Qin, T. ; Ravelli, D. ; Ren, Y.; Ryu, I. ; Sammis, G. M.; Sibi, M. P.; Subramaniann, H.; Suga, S.; Sumino, S. ; Thomson, B.; Yamago, S.; Zhou, M.

Title: Free Radicals: Fundamentals and Applications in Organic Synthesis 2

Print ISBN: 9783132435544; Online ISBN: 9783132435551; Book DOI: 10.1055/b000000086

1st edition © 2021. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This chapter briefly summarizes the concept of radical cascade reactions (RCR). The chapter is divided into two main parts, describing intramolecular and intermolecular radical cascade reactions, which are further classified based on the six types of relay manner (intramolecular RCR) and six commonly used relay molecules (intermolecular RCR), respectively. This simple classification allows readers to understand this area easily and quickly. Features of radical cascade reactions include step-economy and waste minimization, which endow these radical cascades with a bright future.

Key words

free radicals - radical cascade reactions (RCR) - domino reactions - synthetic methods
 
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