Oxidative Allylic Amination Reactions of Unactivated Olefins – At the Frontiers of Palladium and Selenium Catalysis

Alexander Breder

doi:10.1055/s-0033-1340625

Synlett, Table of Contents

Synlett 2014; 25(07): 899-904
DOI: 10.1055/s-0033-1340625

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Oxidative Allylic Amination Reactions of Unactivated Olefins – At the Frontiers of Palladium and Selenium Catalysis

Authors

Alexander Breder*

Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstr. 2, 37077 Göttingen, Germany Fax: +49(551)398699 Email: abreder@gwdg.de

Abstract

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Abstract

The direct oxidative conversion of simple, nonactivated alkenes into allylic amine derivatives represents a profound challenge to contemporary chemical synthesis. This article provides an overview on recent methodological developments and applications in the realm of modern palladium- and selenium-catalyzed oxidative allylic amination reactions.

Key words

alkenes - oxidation - C–N bond construction - transition metals - chalcogens - catalysis

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