Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Sulfonamides

Guo-Fa Dai; Yu-Chuan Song; Fanhua Xiao; Wei-Liang Duan

doi:10.1055/s-0036-1591593

Synthesis, Inhaltsverzeichnis

Synthesis 2018; 50(17): 3506-3512
DOI: 10.1055/s-0036-1591593

paper

Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Sulfonamides

Autor*innen

Guo-Fa Dai

^aSchool of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. of China eMail: fhxiao@sit.edu.cn
Yu-Chuan Song

^aSchool of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. of China eMail: fhxiao@sit.edu.cn
Fanhua Xiao*

^aSchool of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. of China eMail: fhxiao@sit.edu.cn
Wei-Liang Duan*

^bSchool of Chemistry and Chemical Engineering, Yangzhou University, No. 180 Siwangting Road, Yangzhou 225002, Jiangsu Province, P. R. of China eMail: duanwl@yzu.edu.cn

Abstract

Alle Artikel dieser Rubrik

Abstract

A pincer palladium-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated sulfonamides was realized for the synthesis of chiral sulfonamide phosphines with up to 98% ee under mild conditions.

Key words

α,β-unsaturated sulfonamides - asymmetric 1,4-addition - pincer palladium catalyst - chiral phosphine

Volltext

Referenzen

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