4.4.21.13 Silylamines (Update 2013)

Abstract

This review, which updates the original Section 4.4.21, published in 2001, discusses the preparation of silylamines bearing dicoordinate, tricoordinate, tetracoordinate, and pentacoordinate silicon centers. Reaction of chlorosilanes with primary or secondary amines is one of the most conventional methods for the syntheses of these compounds. Reactions of halosilanes with lithium amides, lithium β-diketiminates, and other metalated nitrogen species are also useful. A more recent advance is the dehydrogenative condensation of hydrosilanes with primary or secondary amines using transition-metal or Lewis acid catalysts.

Key words

silylamines - halosilanes - hydrosilanes - amines - diamines - amino alcohols - amides - dehydrogenative condensation - dehydrochlorination - transition-metal-catalyzed reactions

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