31.42 Product Class 42: Arylphosphines and Derivatives

Abstract

This manuscript is a revision of the earlier Science of Synthesis contribution describing methods for the synthesis of arylphosphines. Classical routes to arylphosphines involve the formation of the required C—P bonds from P-electrophilic, P-nucleophilic, and P-radical precursors. Newer methods are based on hydrophosphination and coupling processes catalyzed by transition-metal complexes. Methods involving reductions and decomplexations of tetracoordinate phosphorus precursors and modifications of the carbon skeleton in existing arylphosphines are also included.

Key words

aryl compounds - C—P bonds - coupling reactions - deoxygenation - desulfurization - nucleophilic substitution - nucleophilic addition - phosphines - phosphorus compounds - radical addition - transition metals

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