TY - ECHAP DO - 10.1055/sos-SD-105-00278 SN - 9783132435643 SN - 9783132435667 LA - EN AU - Weinert,C. TI - 5.1.13.3 Germylamines (Update 2020) PB - Georg Thieme Verlag KG CY - Stuttgart PY - 2021 ET - 1st edition UR - http://www.thieme-connect.de/products/ebooks/lookinside/10.1055/sos-SD-105-00278 T3 - Science of Synthesis DA - 2020/11/06 KW - germylamines KW - germanes KW - germanium compounds KW - macrocyclic ligands KW - nitrogen ligands KW - metathesis KW - halo compounds KW - lithium compounds AB - This review describes the synthesis of compounds that have an organogermanium(IV) fragment (R13Ge) attached to a formally anionic nitrogen-containing fragment (R22N−). It is an update to the earlier Science of Synthesis contribution on these compounds (Section 5.1.13) and covers the literature published since 2003. The synthetic methods described include synthesis by metathesis, ligand exchange, and the oxidative addition of germylenes to different substrates. The synthesis of germylamines using heterocumulenes and the preparation of macrocyclic germylamines is also discussed. T2 - Knowledge Updates 2020/3 ER -