NaIO4/NH2OH-mediated Efficient Synthesis of Phosphoroamidates from Anilines and Triethyl Phosphite

E. V. Venkat Shivaji Ramarao; Savita Gat; Rana Chatterjee; Jayshree Solanke; Vasudevan Dhayalan; Rambabu Dandela

doi:10.1055/a-2386-5537

Sustainability & Circularity NOW, Inhaltsverzeichnis

CC BY 4.0 · Sustainability & Circularity NOW 2024; 01: a23865537
DOI: 10.1055/a-2386-5537

Original Article

NaIO₄/NH₂OH-mediated Efficient Synthesis of Phosphoroamidates from Anilines and Triethyl Phosphite

Autor*innen

E. V. Venkat Shivaji Ramarao‡

¹Dr Reddy’s Institute of Life Sciences, University of Hyderabad Campus, Gachibowli, Hyderabad 500 046, India
Savita Gat‡

²Department of Industrial and Engineering Chemistry, Institute of Chemical Technology, Indian Oil Odisha Campus, Samantpuri, Bhubaneswar 751013, India
Rana Chatterjee

²Department of Industrial and Engineering Chemistry, Institute of Chemical Technology, Indian Oil Odisha Campus, Samantpuri, Bhubaneswar 751013, India
Jayshree Solanke

²Department of Industrial and Engineering Chemistry, Institute of Chemical Technology, Indian Oil Odisha Campus, Samantpuri, Bhubaneswar 751013, India
Vasudevan Dhayalan

³Department of Chemistry, National Institute of Technology Puducherry, Karaikal 609609, Puducherry, India
Rambabu Dandela

²Department of Industrial and Engineering Chemistry, Institute of Chemical Technology, Indian Oil Odisha Campus, Samantpuri, Bhubaneswar 751013, India

Abstract

Alle Artikel dieser Rubrik

Abstract

A simple, efficient, and metal-free method was developed for the synthesis of phosphoroamidates. In essence, a mixture of sodium periodate (NaIO₄) and hydroxylamine (NH₂OH⸱HCl) was used in stoichiometric amounts to execute the phosphoramidation reaction of aromatic amines and triethyl phosphites at room temperature, in open air. This method offers a practical synthesis route to afford a diverse range of phosphoroamidates via the construction of P − N bonds, with excellent functional group compatibility and good yields under mild conditions.

Keywords

Metal-free - Sodium periodate (NaIO₄) - Hydroxylamine (NH₂OH⸱HCl) - Available starting substrates - Phosphoroamidates - Room temperature

Bibliographical Record
E. V. Venkat Shivaji Ramarao, Savita Gat, Rana Chatterjee, Jayshree Solanke, Vasudevan Dhayalan, Rambabu Dandela. NaIO₄/NH₂OH-mediated Efficient Synthesis of Phosphoroamidates from Anilines and Triethyl Phosphite. Sustainability & Circularity NOW 2024; 01: a23865537.
DOI: 10.1055/a-2386-5537

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