Transition-Metal-Catalyzed Deuteration via Hydrogen Isotope Exchange

Zhi-Jiang Jiang; Jian-Fei Bai; Zhanghua Gao

doi:10.1055/a-2460-7378

SynOpen, Inhaltsverzeichnis

CC BY 4.0 · SynOpen 2024; 08(04): 328-359
DOI: 10.1055/a-2460-7378

graphical review

Transition-Metal-Catalyzed Deuteration via Hydrogen Isotope Exchange

Autor*innen

Zhi-Jiang Jiang ∗

^aNingboTech-Cuiying Joint Laboratory of Stable Isotope Technology, School of Biological and Chemical Engineering, NingboTech University, Ningbo, 315100, P. R. of China
Jian-Fei Bai

^aNingboTech-Cuiying Joint Laboratory of Stable Isotope Technology, School of Biological and Chemical Engineering, NingboTech University, Ningbo, 315100, P. R. of China
Zhanghua Gao ∗

^aNingboTech-Cuiying Joint Laboratory of Stable Isotope Technology, School of Biological and Chemical Engineering, NingboTech University, Ningbo, 315100, P. R. of China

^bNingbo Cuiying Chemical Technology Co. Ltd., Ningbo, 315100, P. R. of China

Abstract

Alle Artikel dieser Rubrik

Abstract

Direct hydrogen isotope exchange represents a distinctive strategy for deuterium labelling, where the protium is directly replaced by deuterium. In this graphical review, we summarize the progress in deuteration via transition-metal-catalyzed hydrogen isotope exchange. The review is organized according to the mechanism of C–H bond activation relating to the homogeneous catalysis, and heterogeneous catalysis is also discussed according to the catalyst type. Representative mechanistic processes are depicted, and proven cases for tritiation are also highlighted.

Key words

H/D exchange - C–H activation - hydrogen-borrowing - deuterium labelling - heavy water - deuterium gas

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