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Synthesis
DOI: 10.1055/a-2675-3935
Paper

Iron Catalyst and Blue Light Partnership for Selective Desulfurization of Secondary and Primary Thioamides

Qingxin Zhang
1   Univ. Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France, Université de Rennes, Rennes, France (Ringgold ID: RIN27079)
,
Madhi Berro
1   Univ. Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France, Université de Rennes, Rennes, France (Ringgold ID: RIN27079)
,
Christophe Darcel
1   Univ. Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France, Université de Rennes, Rennes, France (Ringgold ID: RIN27079)
› Institutsangaben
Gefördert durch: National Research Agency ANR-22-PESP-0006
Gefördert durch: China Scholarship Council
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Commercially available Iron(0) Fe2(CO)9 pre-catalyst can promote the selective desulfurization of secondary and primary carboxamides leading to the corresponding secondary amines and nitriles, respectively. The reaction is conducted under hydrosilylation conditions using phenylsilane or diethylsilane blue LED irradiation (2x24W, 450-460 nm) at ambient conditions.



Publikationsverlauf

Eingereicht: 20. Juni 2025

Angenommen nach Revision: 03. August 2025

Accepted Manuscript online:
04. August 2025

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