π–π Interactions as Noncovalent Tools in Selective Catalysis

Jinho Kim; Jangjoo Kim; Jeonghyo Lee

doi:10.1055/a-2705-6850

Synthesis, Inhaltsverzeichnis

Synthesis 2026; 58(01): 17-31
DOI: 10.1055/a-2705-6850

Short Review

π–π Interactions as Noncovalent Tools in Selective Catalysis

Autor*innen

Jinho Kim‡

¹Department of Chemistry and Research Institute for Convergence of Basic Science, Hanyang University, Seoul (Ringgold ID: RIN26716)
Jangjoo Kim‡

¹Department of Chemistry and Research Institute for Convergence of Basic Science, Hanyang University, Seoul (Ringgold ID: RIN26716)
Jeonghyo Lee

¹Department of Chemistry and Research Institute for Convergence of Basic Science, Hanyang University, Seoul (Ringgold ID: RIN26716)

Abstract

Alle Artikel dieser Rubrik

Abstract

This short review describes recent advances in π–π stacking interaction-enabled catalysis for selective transformations. Owing to their charge-independent and spatially accessible nature, π–π interactions have been utilized to control chemo-, regio-, and stereoselectivity in a range of transformations. Selected examples are presented to illustrate how these noncovalent forces modulate transition-state geometry or stabilize key intermediates in C–C, C–O, and C–N bond formations, as well as in reductions and hydrogenation reactions.

Keywords

π–π Interactions - Noncovalent interactions - Selective catalysis bond formation - Selective reduction

Volltext

Referenzen

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