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Synfacts 2008(12): 1306-1306
DOI: 10.1055/s-0028-1087323
DOI: 10.1055/s-0028-1087323
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Diastereoselective Radical Cyclization Towards Piperidinones
E. Godineau, K. Schenk, Y. Landais*
University Bordeaux 1, Talence, France; University of Lausanne, Switzerland
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. November 2008 (online)
Significance
The authors report their findings on the radical cyclization of enoximes bearing an allylic chiral substitutent, extending on a preliminary study (Org. Lett. 2008, 8, 4871). Investigation of the role of steric and electronic parameters of the starting materials and further insight into the mechanism of the transformation are outlined in this comprehensive report.