Titanium-Mediated Reductive Cross-Coupling of Aliphatic Imines

M. A. Tarselli; G. C. Micalizio

doi:10.1055/s-0029-1218435

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Synfacts 2010(1): 0083-0083
DOI: 10.1055/s-0029-1218435

Metal-Mediated Synthesis

Titanium-Mediated Reductive Cross-Coupling of Aliphatic Imines

Contributor(s): Paul Knochel, Andreas J. Wagner
M. A. Tarselli, G. C. Micalizio*
The Scripps Research Institute, Jupiter, USA

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Publication History

Publication Date:
21 December 2009 (online)

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Significance

The authors disclose a procedure for the coupling of aliphatic imines with allylic and allenic alkoxides, giving rise to homoallyl or butadienyl amines in good yields.