Synfacts 2011(3): 0307-0307  
DOI: 10.1055/s-0030-1259418
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Palladium-Catalyzed Propargylic Substitution with Phosphorus Nucleophiles

Contributor(s): Paul Knochel, Andreas J. Wagner
M. Kalek, T. Johansson, M. Jezowska, J. Stawinski*
Stockholm University, Sweden and Polish Academy of Sciences, Poznan, Poland
Further Information

Publication History

Publication Date:
16 February 2011 (online)


A new palladium(0)-catalyzed reaction of propargylic derivatives with phosphorus nucleophiles is reported. Various allenyl phosphonates are obtained with defined stereochemistry both in the allenic and the phosphonate moiety.