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Synthesis 2011(11): 1771-1776  
DOI: 10.1055/s-0030-1260021
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

A One-Pot β-Chloro-N′-tosylamidination of Olefins with Chloramine-T

Annamalai Murali, Suman Kumar Sen, Sundarababu Baskaran*
Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India
Fax: +91(44)22570545; e-Mail: sbhaskar@iitm.ac.in;
Further Information

Publication History

Received 5 March 2011
Publication Date:
28 April 2011 (online)

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Abstract

A new method for the direct synthesis of β-chloro-N′-tosylamidines from olefins using chloramine-T and trifluoromethanesulfonic acid is described.

Key words

olefins - chloramine-T - amidination - amidines - amines

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