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Synthesis 2011(16): 2590-2594
DOI: 10.1055/s-0030-1260075
DOI: 10.1055/s-0030-1260075
SPECIALTOPIC
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Mediated Olefination of 2-(tert-Butyldimethylsilyl)pyridine by sp³ C-H Activation
Weitere Informationen
Received
9 April 2011
Publikationsdatum:
17. Juni 2011 (online)
Publikationsverlauf
Publikationsdatum:
17. Juni 2011 (online)
Abstract
An unprecedented direct alkenylation of 2-(tert-butyldimethylsilyl)pyridine with acrylates through palladium-mediated C-H activation on a nonacidic sp³ carbon is reported. This method provides an efficient approach to allylsilanes.
Key words
palladium - olefination - pyridine
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