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Synfacts 2011(7): 0767-0767  
DOI: 10.1055/s-0030-1260507
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Ni-Catalyzed Multicomponent Reaction of Vinylcyclopropane, Alkyne, and Me2Zn

Contributor(s): Paul Knochel, Andreas K. Steib
T. Mori, T. Nakamura, M. Kimura*
Nagasaki University, Japan
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Publikationsdatum:
17. Juni 2011 (online)

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Significance

A new nickel-catalyzed regio- and stereocontrolled three-component coupling reaction of alkynes, Me2Zn, and vinyloxacyclopropanes or vinylcyclopropanes to yield dienyl homo­allylalcohols and α-dienyl malonates is described.