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Synfacts 2011(8): 0884-0884
DOI: 10.1055/s-0030-1260717
DOI: 10.1055/s-0030-1260717
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Radical Alkylphosphanylation of Olefins
M.-C. Lamas, A. Studer*
University of Münster, Germany
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Juli 2011 (online)
Significance
In this work, the first radical alkylphosphanylation reaction of activated olefins, such as α,β-unsaturated esters, amides, imides, nitriles and sulfones is described. This reaction uses Me3SnPPh2 and Me3SiPPh2 as trapping and chain-transfer reagents in combination with secondary and tertiary alkyl iodides.