New Sulfonamide-Olefin Ligand for Rh-Catalyzed 1,4-Addition
S.-S. Jin, H. Wang, M.-H. Xu*
Shanghai Institute of Materia Medica, P. R. of China
19. August 2011 (online)
A novel sulfonamide-olefin hybrid ligand with a simple and flexible structure was easily accessed that shows great enantioselective control in the rhodium-catalyzed 1,4-addition of arylboronic acids to α,β-unsaturated cyclic carbonyl compounds.