[2+2+2] for Chain-Growth
Polymerization

Y. Sugiyama; R. Kato; T. Sakurada; S. Okamoto

doi:10.1055/s-0030-1261025

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Synfacts 2011(9): 0964-0964
DOI: 10.1055/s-0030-1261025

Synthesis of Materials and Unnatural Products

[2+2+2] for Chain-Growth Polymerization

Contributor(s): Timothy M. Swager, Ggoch Ddeul Han
Y. Sugiyama, R. Kato, T. Sakurada, S. Okamoto*
Kanagawa University, Yokohama, Japan

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Publikationsverlauf

Publikationsdatum:
19. August 2011 (online)

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Significance

Linear polymers were formed from yne-diyne monomers via catalytic alkyne cycloaddition in a chain-growth manner. Two monomers with significantly different reactivity produced a block copolymer by one-shot polymerization.