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Synthesis 2012; 44(8): 1190-1198
DOI: 10.1055/s-0031-1290591
DOI: 10.1055/s-0031-1290591
special topic
Intramolecular Olefin Diamination for the Stereoselective Synthesis of 3-Aminopiperidines
Weitere Informationen
Publikationsverlauf
Received: 15. Februar 2012
Accepted: 24. Februar 2012
Publikationsdatum:
28. März 2012 (online)
Abstract
A general method for the direct intramolecular diamination of terminal olefins is presented. The reaction, mediated by hypervalent iodine oxidants, produces substituted 3-aminopiperidine scaffolds with high regio- and stereoselectivity, rendering this process relevant to both medicinal chemistry and natural products synthesis.
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