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Synthesis 2013; 45(5): 694-702
DOI: 10.1055/s-0032-1318151
DOI: 10.1055/s-0032-1318151
paper
Scope of the Desulfinylative Palladium-Catalyzed Cross-Coupling of Aryl Sulfinates with Aryl Bromides
Further Information
Publication History
Received: 20 November 2012
Accepted after revision: 10 January 2013
Publication Date:
04 February 2013 (online)
Dedicated to the memory of Keith Fagnou
Abstract
Herein is described the full scope of a desulfinylative cross-coupling of aryl sulfinates with aryl bromides. Optimized conditions were established and a bidentate phosphine ligand was found to be the key in obtaining good cross-coupling yields. Preliminary efforts to elucidate the reaction mechanism suggest that a Pd(0)-catalyzed mechanism is operative.
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- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
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