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Synlett 2013; 24(11): 1371-1376
DOI: 10.1055/s-0033-1338804
DOI: 10.1055/s-0033-1338804
letter
Gold(I)-Catalyzed Diketonization of Alkynes and Its Application for the One-Pot Synthesis of Quinoxaline Derivatives
Further Information
Publication History
Received: 06 March 2013
Accepted after revision: 19 April 2013
Publication Date:
05 June 2013 (online)
Abstract
A gold(I)-catalyzed oxidative diketonization of alkynes by water in the presence of Selectfluor has been achieved. The application of the present protocol for the one-pot synthesis of quinoxaline derivatives from alkynes and o-phenylenediamines has also been successful.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
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For selected recent review articles on homogeneous gold catalysis, see:
For review articles on the gold catalysis involving Au(I)/Au(III) redox catalytic cycle, see:
Gold-catalyzed synthesis of 1,2-dicarbonyl compounds from alkynes using expensive oxygen sources, see:
For other transition-metal-catalyzed oxidative diketonization of alkynes to access 1,2-diketones, see for example: