Recent Advances in Metal-Catalyzed Asymmetric Mannich Reactions

Abstract

In this review, recent works on metal-catalyzed asymmetric Mannich, aza-Henry and vinylogous Mannich reactions are described. The asymmetric Mannich reaction is one of the most powerful methodologies among the carbon–carbon bond-forming reactions, and provides direct access to a wide range of optically active natural products with useful biological properties.

1 Introduction

2 Catalytic Asymmetric Mannich Reactions

2.1 BINOL Ligands

2.2 BINAP Ligands

2.3 Bisoxazoline Ligands

2.4 Pyridine Bisoxazoline Ligands

2.5 Diamine Ligands

2.6 P,N-Ligands

2.7 P,S-Ligands

2.8 P,P-Ligands

2.9 N,N-Ligands

2.10 Miscellaneous

3 Asymmetric Aza-Henry Reactions

3.1 BINOL Ligands

3.2 Bisoxazoline Ligands

3.3 N,N-Ligands

3.4 Miscellaneous

4 Asymmetric Vinylogous Mannich Reactions

5 Conclusion

Key words

asymmetric Mannich reaction - aza-Henry reactions - vinylogous Mannich reactions - carbon–carbon bond-forming reactions - metal complexes

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