Molecular Iodine Mediated Regioselective Synthesis of Pyranocoumarins and Bis-Fused Benzo-2H-pyran Derivatives

K. C. Majumdar; Biswajit Sinha; Inul Ansary; Sintu Ganai; Debankan Ghosh; B. Roy; B. Sridhar

doi:10.1055/s-0033-1341027

Synthesis, Table of Contents

Synthesis 2014; 46(13): 1807-1814
DOI: 10.1055/s-0033-1341027

paper

Molecular Iodine Mediated Regioselective Synthesis of Pyranocoumarins and Bis-Fused Benzo-2H-pyran Derivatives

Authors

K. C. Majumdar*

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
Biswajit Sinha

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
Inul Ansary

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
Sintu Ganai

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
Debankan Ghosh

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
B. Roy

^aDepartment of Chemistry, University of Kalyani, Kalyani 741235, W. B., India Email: kcm@klyuniv.ac.in Email: kcm_ku@yahoo.co.in
B. Sridhar

^bLaboratory of X-ray crystallography, IICT Hyderabad, Hyderabad 500007, India

Abstract

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Abstract

A simple and straightforward approach for the regioselective synthesis of pyranocoumarin and bis-fused benzo-2H-pyran derivatives using mild, easy to handle, and cheaper molecular iodine mediated heterocyclization is described.

Key words

molecular iodine - 6-endo-dig - electrophilic cylization - bis-fused benzo-2H-pyrans - pyranocoumarins

Full Text

References

References
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15 CCDC-809664 contains the supplementary crystallographic data of the compound 17a. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44(1223)336033; E-mail: deposit@ccdc.cam.ac.uk.

Supplementary Material

Supporting Information (PDF)