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Synthesis 2015; 47(20): 3207-3211
DOI: 10.1055/s-0034-1380439
DOI: 10.1055/s-0034-1380439
paper
A Facile and Selective Procedure for Oxidation of Hydroquinones using Silica Gel Supported Catalytic Cerium(IV) Ammonium Nitrate
Further Information
Publication History
Received: 26 April 2015
Accepted after revision: 15 May 2015
Publication Date:
09 July 2015 (online)
Abstract
A new procedure for oxidation of hydroquinones to quinones using a silica gel supported cerium(IV) ammonium nitrate-NaBrO3 reagent has been developed. This simple, easy to prepare and use, heterogeneous reagent is highly selective towards oxidation of 1,4-dihydroxybenzenes and produces high yields of quinones. Waste generated by using this procedure is minimal.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380439.
- Supporting Information
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