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Synthesis 2016; 48(06): 816-827
DOI: 10.1055/s-0035-1561313
DOI: 10.1055/s-0035-1561313
feature
Enantioselective Vicinal Diacetoxylation of Alkenes under Chiral Iodine(III) Catalysis
Further Information
Publication History
Received: 17 November 2015
Accepted after revision: 14 December 2015
Publication Date:
13 January 2016 (online)
Abstract
A procedure for the intermolecular enantioselective dioxygenation of alkenes under iodine(III) catalysis has been developed. This protocol employs Selectfluor as the terminal oxidant together with a defined C 2-symmetric aryl iodide as the organocatalyst. This enantioselective reaction proceeds under mild conditions and converts a series of terminal and internal styrenes into the corresponding vicinal diacetoxylation products with up to 96% ee.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561313.
- Supporting Information
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