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Synthesis 2017; 49(17): 3937-3944
DOI: 10.1055/s-0036-1589011
DOI: 10.1055/s-0036-1589011
special topic
C–H and N–H Bond Annulation of Benzamides with Isonitriles Catalyzed by Cobalt(III)
Financial support provided by SERB (EMR2016/000136) to support this research work is gratefully acknowledged. D.K. thanks IITK, N.B. and Pardeep express gratitude to CSIR for their fellowships.Weitere Informationen
Publikationsverlauf
Received: 03. März 2017
Accepted after revision: 04. April 2017
Publikationsdatum:
11. Mai 2017 (online)
Published as part of the Special Topic Cobalt in Organic Synthesis
In memory of Prof. Shunsuke Murahashi for pioneering work in cobalt-catalyzed C–H bond functionalization
Abstract
A simple efficient, atom-economical procedure was developed for the cobalt-catalyzed C–H bond annulation of benzamides with isonitriles under mild conditions. The reaction tolerates a variety of functional group including heterocycles. Diverse 3-(alkylimino)-2-quinolin-8-yl-2,3-dihydro-1H-isoindol-1-ones were synthesized using isonitriles as the C1 source through C–H and N–H bond annulation via C–H bond activation in a ‘green’ solvent. Vinylamides were also used similarly with tert-butyl isonitrile to give 3-(tert-butylimino)-1-quinolin-8-yl-1H-pyrrol-2(5H)-ones.
Supporting Information
- Supporting information for this article is available online at https://doi.org /10.1055/s-0036-1589011.
- Supporting Information
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