DOI: 10.1055/s-0036-1589101
© Georg Thieme Verlag Stuttgart · New York

Nickel-Catalyzed Cross-Coupling of Functionalized Organo­manganese Reagents with Aryl and Heteroaryl Halides Promoted by 4-Fluorostyrene

Andreas D. Benischkea, Alexandre Desaintjeanb, Thomas Julia, Gérard Cahiezb, Paul Knochel*a
  • aDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5–13, 81377 München, Germany
  • bInstitut de Recherche de Chimie Paris, CNRS, Chimie Paris Tech, 11 Rue Pierre et Marie Curie, 75005 Paris, France   Email:
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Publication History

Received: 25 July 2017

Accepted after revision: 03 August 2017

Publication Date:
30 August 2017 (eFirst)


A catalytic system consisting of Ni(acac)2 (5 mol%) and 4-fluorostyrene (20 mol%) allows a convenient cross-coupling of functionalized organomanganese reagents with a variety of aryl and heteroaryl halides leading to polyfunctionalized diaryl- and arylheteroarylmethane derivatives.

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