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Synthesis 2018; 50(09): 1737-1749
DOI: 10.1055/s-0036-1591777
DOI: 10.1055/s-0036-1591777
review
Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis
Further Information
Publication History
Received: 29 September 2017
Accepted after revision: 21 November 2017
Publication Date:
20 March 2018 (online)
Abstract
Herein, copper-catalyzed borylative and silylative transformations of allenes using borylcopper or silylcopper as the active catalytic species are described. First, the synthesis and characterization of borylcopper and silylcopper complexes are briefly introduced. Next, the borylative transformations of allenes are summarized including hydroboration, carboboration, and borylative allylation of carbonyl compounds. We next deal with the silylative transformations of allenes such as hydrosilylation, carbosilylation, and silylative allylation of carbonyl compounds.
1 Introduction
2 Synthesis of Borylcopper and Silylcopper Complexes
3 Borylative Transformations
4 Silylative Transformations
5 Conclusions and Future Outlook
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