Synlett 2018; 29(09): 1219-1222
DOI: 10.1055/s-0036-1591955
letter
© Georg Thieme Verlag Stuttgart · New York

One-Pot Reaction To Form Hydrophosphorylated Fullerenes from C60 and Ph3–n PCl n /ROH

Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Xiuying Xie
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Chang-Qiu Zhao
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Xianqiang Huang
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Junhong Zhang
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Ji-Yuan Du
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Jie Yang
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
,
Chun-Lin Ma
Institution of Functional Organic Molecules and Materials, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. of China   Email: [email protected]
› Author Affiliations
This study was financially supported by NSFC (Nos. 21502084, 21401094, 21602094)
Further Information

Publication History

Received: 15 January 2018

Accepted after revision: 20 February 2018

Publication Date:
19 March 2018 (online)


Abstract

Hydrophosphorylated fullerene derivatives were readily prepared in one step by treating C60 with Ph3 n PCl n (n = 1–3) and ROH (R = H, alkyl). The one-pot reaction could be performed under mild conditions with moderate to good yields. Dichlorophenylphosphine and alcohols exhibited unexpected reactivity towards C60. A possible reaction mechanism involving the formation of P(III)–OH in situ was proposed to explain the experimental results.

Supporting Information

 
  • References and Notes


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