Cu(III)-Mediated Aerobic Oxidations

Abstract

Cu^III species have been invoked in many copper-catalyzed transformations including cross-coupling reactions and oxidation reactions. In this review, we will discuss seminal discoveries that have advanced our understanding of the Cu^I/Cu^III redox cycle in the context of C–C and C–heteroatom aerobic cross-coupling reactions, as well as C–H oxidation reactions mediated by Cu^III–dioxygen adducts.

1 General Introduction

2 Early Examples of Cu^III Complexes

3 Aerobic Cu^III-Mediated Carbon–Heteroatom Bond-Forming Reactions

4 Aerobic Cu^III-Mediated Carbon–Carbon Bond-Forming Reactions

5 Bioinorganic Studies of Cu^III Complexes from Cu^I and O₂

5.1 O₂ Activation

5.2 Biomimetic Cu^III Complexes from Cu^I and Dioxygen

5.2.1 Type-3 Copper Enzymes and Dinuclear Cu Model Complexes

5.2.2 Particulate Methane Monooxygenase and Di- and Trinuclear Cu Model Complexes

5.2.3 Dopamine–β-Monooxygenase and Mononuclear Cu Model Complexes

6 Conclusion

Key words

Cu(III) oxidation - copper–oxygen complexes - biomimetic Cu(III) species - aerobic oxidations

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