Modification of Azobenzenes by Cross-Coupling Reactions

Abstract

Azobenzenes are among the most extensively used molecular switches for many different applications. The need to tailor them to the required task often requires further functionalization. Cross-coupling reactions are ideally suited for late-stage modifications. This review provides an overview of recent developments in the modification of azobenzene and its derivatives by cross-coupling reactions.

1 Introduction

2 Azobenzenes as Formally Electrophilic Components

2.1 Palladium Catalysis

2.2 Nickel Catalysis

2.3 Copper Catalysis

2.4 Cobalt Catalysis

3 Azobenzenes as Formally Nucleophilic Components

3.1 Palladium Catalysis

3.2 Copper Catalysis

3.3 C–H Activation Reactions

4 Azobenzenes as Ligands in Catalysts

5 Diazocines

5.1 Synthesis

5.2 Cross-Coupling Reactions

6 Conclusion

Key words

azobenzene - diazocine - molecular switches - cross-coupling reactions - C–H activation - metal-catalyzed

Publikationsverlauf

Eingereicht: 07. Oktober 2020

Angenommen nach Revision: 19. November 2020

Artikel online veröffentlicht:
28. Januar 2021

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