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Synthesis 2023; 55(10): 1586-1592
DOI: 10.1055/s-0042-1751435
paper

Hydration of Arylacetylenes Promoted by the Photothermal ­Effect of Gold Nanoparticles

Hongyan Yuan
a   Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
,
Kaixuan Su
a   Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
,
Mengyuan Ji
a   Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
,
Huimin Xue
a   Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
,
Hongyu Chen
b   School of Science, Westlake University, Hangzhou 310023, Zhejiang, China
,
Yanhua Zhang  ∗
a   Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
› Author AffiliationsThe authors thank the National Natural Science Foundation of China (Grant Nos. 21673117 and 91956109), Zhejiang Provincial Natural Science Foundation of China (Grant No. 2022XHSJJ002), and the Start-up Fund from Nanjing Tech University (Grant Nos. 39837126 and 39837102).
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Abstract

With the help of the photothermal effect of gold nanoparticles (AuNPs), the hydration of the arylacetylenes to synthesize carbonyl compounds is successfully achieved. The reaction proceeds smoothly for various substrates and the ketone products are obtained in good isolated yields up to 91%. The successful gram-scale and sunlight-exposure experiments illustrate the potential application of this method in the future organic syntheses.

Key words

arylacetylenes - Au nanoparticles - hydration - photothermal effect - sunlight

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/s-0042-1751435.
  • Supporting Information


Publication History

Received: 22 December 2022

Accepted after revision: 27 February 2023

Article published online:
24 March 2023

© 2023. Thieme. All rights reserved

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