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Synlett 1990; 1990(5): 271-272
DOI: 10.1055/s-1990-21061
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Elaboration of 1,2,3,4-Tetrahydroquinoline via η2-Imine complexes of Zirconocene

N. Coles* , R. J. Whitby, J. Blagg
  • *Chemistry Department, The University, Southampton S09 5NH, England
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Publikationsdatum:
08. März 2002 (online)

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1,2,3,4-Tetrahydroquinoline is converted into the zirconocene η2-imine complexes 2 or 3 via a C-H activation process. These complexes react efficiently with a range of unactivated alkenes, alkynes and allenes to afford azazircona-cyclopentanes. Workup with methanol gives the 2-substituted tetrahydroquinolines in good yield.