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Synthesis 1990; 1990(1): 27-32
DOI: 10.1055/s-1990-26777
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A New Highly Chemo- and Regioselective Alkoxycarbonylation of Amino Alcohols and polyols

Monique Allainmat* , Paul L'Haridon, Loîc Toupet, Daniel Plusquellec
  • *E.N.S.C.R., Laboratoire de Chimie Organique et des Substances Naturelles, U. R. A. 482, Avennue du Général Leclerc, F-35700 Rennes, France
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Publikationsdatum:
17. September 2002 (online)

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The alkoxycarbonylating carbamates 1 and 2 are readily prepared and reacted under mild conditions with polyfunctional substrates, e.g. amino acids, unsymmetrical diols, and unprotected carbohydrates (D-glucosamine and methyl α-D-glucoside), thus affording carbamates or monocarbonates in good yields and with high chemo- and regioselectivity.

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