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Synthesis 1990; 1990(2): 127-128
DOI: 10.1055/s-1990-26807
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Trimethylammonium Chlorochromate (TMACC). A New, Mild, Stable, Efficient and Inexpensive Chromium(VI) Oxidation Reagent

Shrinivas P. Acharya* , Ramakrishna A. Rane
  • *Acharya Research Centre (P) Ltd., Division of Acharya Chemicals, W-41, MIDC Morivli, Ambernath 421501, Maharashtra, India
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Publikationsdatum:
17. September 2002 (online)

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A mild and stable new chromium(VI) reagent from trimethylamine is described. Trimethylammonium chlorochromate (TMACC, 1) alone or in conjunction with molecular sieves oxidizes alcohols in aprotic solvents to carbonyl compounds efficiently in quantitative yields. It oxidizes selectively allylic alcohols to corresponding aldehydes without isomerization. Dodecanol (2b) is oxidized to dodecanal (3b) in good yield.