PDF herunterladen
Synthesis 1990; 1990(6): 459-460
DOI: 10.1055/s-1990-26903
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of 2- and 3-Nitrooxypropanol by Chemoselective Reduction of Methyl 2-and 3-Nitrooxypropionoate

Toshihisa Ogawa* , Atsuro Nakazato, Masakazu Sato, Katsuo Hatayama
  • *Research Center, Taisho Pharmaceutical Co., Ltd., 1-403 Yoshino-cho, Omiya, Saitama 330, Japan
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
17. September 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Highly chemoselective reduction of methyl 2- and 3-nitro-oxypropionate (9) and (12) with calcium borohydride was accomplished to give the desired 2- and 3-nitrooxypropanols (6 and 13) in good yields without affecting the nitrooxy group.

      >