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Synlett 1994; 1994(2): 109
DOI: 10.1055/s-1994-22756
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A New Synthesis of Aldehydes from Ketones Utilizing Trimethylsilyldiazomethane

Kazuhiro Miwa* , Toyohiko Aoyama, Takayuki Shioiri
  • *Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467, JAPAN
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Publication Date:
22 March 2002 (online)

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Reaction of lithium trimethylsilyldiazomethane with aliphatic ketones in the presence of excess diisopropylamine afforded enamines, which were readily converted to the corresponding aldehydes in good to moderate yields.

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