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Synlett 1994; 1994(7): 561-562
DOI: 10.1055/s-1994-22930
DOI: 10.1055/s-1994-22930
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Regioselective Synthesis of Alkenyl Sulfides from Alkenyl Triflates Using Palladium(0) as Catalyst
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Publication History
Publication Date:
18 September 2002 (online)
Secondary alkenyl triflates 2, easily obtained from the corresponding ketones 1, react with lithium thiolates in the presence of Pd(PPh3)4 to form secondary alkenyl sulfides 3 regioselectively (but not fully stereospecifically) in good to excellent yields.