Synthesis of Di- or Tetrafunctionalized Phosphorus Macrocycles

Joëlle Mitjaville; Anne-Marie Caminade; Jean-Pierre Majoral

doi:10.1055/s-1995-4020

Synthesis 1995; 1995(8): 952-956
DOI: 10.1055/s-1995-4020

paper

© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of Di- or Tetrafunctionalized Phosphorus Macrocycles

Joëlle Mitjaville, Anne-Marie Caminade, Jean-Pierre Majoral^*

^*Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, F-31077 Toulouse Cedex, France, Fax +33(61)553003

Abstract

als PDF herunterladen Alle Artikel dieser Rubrik

The reaction of functionalized phosphodihydrazides RP(X)[NMeNH₂]₂ (R=Cl, N₃) (1) with organic (2) or phosphorus (4) dialdehydes leads to the synthesis of di- or tetrafunctionalized phosphorus macrocycles 3a-d, 5a-h in good yield. PCl containing macrocycles are quantitatively converted to PN₃ containing macrocyclic with sodium azide. All compounds are useful precursors of cryptands and multimacrocyclic species.

Functionalized phosphorus macrocycles precursors of cryptands and multimacrocyclic species

PDF (434 kb)