Download PDF
Synthesis 1996; 1996(3): 357-360
DOI: 10.1055/s-1996-4217
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Simple Route to Enantiopure Fluorocyclohexenones

Hilmar Weinmann, Ekkehard Winterfeldt*
  • *Institut für Organische Chemie der Universität Hannover, Schneiderberg 1B, D-30167 Hannover, Germany
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

The 4-fluoro substituted cyclohexadienone 10 was shown to undergo a very efficient differentiation of enantiotopic double bonds in a Diels-Alder cycloaddition process. Epoxidation followed by thermal retro reaction generated the enantiopure fluorocyclohexenone 13.

enantiopure cyclohexenones - differentiation of enantiotopic groups - Diels-Alder Cycloaddition