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Synlett 1996; 1996(2): 169-170
DOI: 10.1055/s-1996-5362
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Efficient Syntheses of Amadori Rearrangement Compounds

Tsuyoshi Iwamoto, Toshiyuki Kan, Shigeo Katsumura, Yasufumi Ohfune*
  • *Suntory Institute for Bioorganic Research, Shimamoto-cho, Osaka 618, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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Various types of 1-amino-1-deoxy-2-ketoses, Amadori rearrangement compounds, have bee synthesized using a reduction amination of the 1-formyl derivative (3), prepared from 2,3:4,5-di-O-isopropylidene-D-fructopyranose (2), with unprotected or partially protected amino acids in a few steps.

amadori rearrangement compound - 1-amino-1-deoxy-2-ketose - reductive amination - deprotection

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