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Synlett 1996; 1996(8): 729-730
DOI: 10.1055/s-1996-5510
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Reaction of C60 with α-Diazoketones: Methano- and Dihydrofuranofullerenes

Hans Jürgen Bestmann* , Claus Moll, Carsten Bingel
  • *Institut für Organische Chemie der Universität Erlangen-Nürnberg, Henkestr. 42, D-91054 Erlangen, Germany
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Publication History

Publication Date:
31 December 2000 (online)

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The reaction of C60 2 with α-diazoketones 1 leads to 6,6-bridged, closed 1,2-methano[60]fullerenes 4a - e and - after their rearrangement on the C60 surface - to 2’-substituted 6,6-bridged, closed 1,2-dihydro-(4’,5’-dihydrodurano)-[60]fullerenes 5a, d, e.

Methanofullerenes - Dihydrofuranofullerenes

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