Download PDF
Synlett 1996; 1996(9): 893-894
DOI: 10.1055/s-1996-5608
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Novel, Stereocontrolled Synthesis of 1,2-trans-Cyclopropanes: Cyclopropyl Boronate Esters as Partners in Suzuki Couplings with Aryl Halides

Jens P. Hildebrand, Stephen P. Marsden*
  • *Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, e-mail: s.marsden@ic.ac.uk
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A novel, stereospecific synthesis of 1,2-trans-disubstituted cyclopropanes is described, based upon the palladium (0) mediated cross-coupling of cyclopropyl boronic esters with aryl halides. This work forms the basis of a proposed new asymmetric synthesis of cyclopropanes.

cyclopropane - palladium - Suzuki - cyclopropyl boronate

      >