Abstract
A methyl group at the aromatic nucleus can be oxidized to the corresponding carboxylic
acid directly in the presence of N-bromosuccinimide (NBS) under photoirradiation. By considering both the promoting
effect of oxygen and a catalytic amount of NBS, aerobic oxidation via hydroperoxide,
which is thought to be generated by abstraction of a hydrogen with a bromo radical
from NBS, proceeded.
Key words
oxidations - methyl group -
N-bromosuccinimide - photoirradiation - molecular oxygen
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