Simple and Improved Procedure for the Regioselective Acylation of Aromatic Ethers with Carboxylic Acids on the Surface of Graphite in the Presence of Methanesulfonic Acid

Mona Hosseini Sarvari; Hashem Sharghi

doi:10.1055/s-2004-831162

PAPER

Simple and Improved Procedure for the Regioselective Acylation of Aromatic Ethers with Carboxylic Acids on the Surface of Graphite in the Presence of Methanesulfonic Acid

Mona Hosseini Sarvari, Hashem Sharghi*
Department of Chemistry, Faculty of Science, Shiraz University, Shiraz 71454, Iran
e-Mail: sharghi@chem.susc.ac.ir;

Abstract

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Abstract

Friedel-Crafts acylation of aromatic compounds such as anisole has been successfully carried out using the combination of graphite with MeSO₃H. Both aromatic and aliphatic carboxylic acids reacted smoothly under the conditions to afford the corresponding aromatic ketones in high yield.

Keyword

Friedel-Crafts acylation - acylations - graphite - regioselectivity - carboxylic acids

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References

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