Regioselective Carbon-Carbon Bond Cleavage of an Open-Cage Diketone Derivative of [60]Fullerene by Reaction with Aromatic Hydrazones

Sho-ichi Iwamatsu; Toshiki Kuwayama; Kaoru Kobayashi; Shigeru Nagase; Shizuaki Murata

doi:10.1055/s-2004-834891

SHORTPAPER

Regioselective Carbon-Carbon Bond Cleavage of an Open-Cage Diketone Derivative of [60]Fullerene by Reaction with Aromatic Hydrazones

Sho-ichi Iwamatsu*^a, Toshiki Kuwayama^a, Kaoru Kobayashi^b, Shigeru Nagase^b, Shizuaki Murata*^a,c
^a Graduate School of Environmental Studies, Nagoya University, Nagoya, 464-8601, Japan
Fax: +81(52)7894765; e-Mail: iwmt@urban.env.nagoya-u.ac.jp;
^b Institute for Molecular Science, Okazaki, 444-8585, Japan
^c CREST, Japan Science and Technology Agency (JST), Japan

Abstract

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Abstract

The addition reaction of aromatic hydrazone to the diketone derivative of C₆₀ occurred with a regioselective C-C bond scission to afford a ring-expanded product having a 16-membered ring orifice.

Key words

fullerenes - cleavage - ring expansion - hydrazones

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References

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