Abstract
Chiral imidazolium salts that can be classified as ionic liquids (ILs) were derived
from the ‘chiral pool’ precursors camphor, β-pinene, and tartaric acid. ILs containing
chiral imidazolium cations as well as chiral anions were synthesized. Furthermore,
the anion of the IL 1-methyl-3-[(S)-2′-methylbutyl]imidazolium tosylate was substituted on an ion-exchange resin for
the chiral (S)-camphorsulfonate anion thus forming the first well-characterized ‘doubly chiral’
IL.
Keywords
imidazolium salts - ionic liquids - chiral anions, chiral cations
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