Preparation and Synthetic Transformation of Alkenyl Carbamates into Vinyl Zirconocene Derivatives

Helena Chechik-Lankin; Ilan Marek

doi:10.1055/s-2005-918436

PAPER

Preparation and Synthetic Transformation of Alkenyl Carbamates into Vinyl Zirconocene Derivatives

Helena Chechik-Lankin, Ilan Marek*
The Mallat Family Laboratory in Organic Chemistry, Department of Chemistry, Institute of Catalysis Science and Technology, The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32 000, Israel
e-Mail: chilanm@tx.technion.ac.il;

Abstract

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Abstract

The carbocupration reaction of alkynyl carbamates leads to the stereospecific preparation of polysubstituted alkenyl carbamates. Subsequent treatment of these enol carbamates with the Negishi reagent gave the corresponding vinyl zirconocene species.

Keywords

alkynyl carbamates - vinyl zirconocene derivatives - organocopper reagents

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